The multinomial probit is an extension of the probit regression. The dependent variable can take on 3 or more unordered values. The modell does not have to fulfill the IIA Assumption.
The multinomial probit regression can be used to model the probability that an observation is a member of a given class out of a set of >2 classes. It can be contrasted with the multinomial logit regression: They are otherwise similar, but use different link functions.
Some references:
Long, S. J., & Freese, J. (2014). Regression Models for Categorical Dependent Variables Using Stata. Texas: Stata Press.
McFadden, D. (1973). Conditional Logit Analysis of Qualitative Choice Behavior. In Frontiers in Econometrics (pp. 105–142). New York: Academic Press.