Could anyone offer a simple example of an existent process?
A well-known theorem which guarantees the existence of a stochastic process ${(X_n)}_{n \geqslant 1}$, say with $\mathbb{R}$-valued random variables $X_n$, is the Daniell-Kolmogorov extension theorem. A typical application of this theorem gives the existence of a sequence of independent random variables ${(X_n)}_{n \geqslant 1}$, with $X_n$ following any probability law (possibly depending on $n$).
Here is the statement of this theorem. Denote by $\mathcal{B}_n$ the Borel $\sigma$-field on $\mathbb{R}^n$. Suppose that for every $n \geqslant 1$ we have a probability measure $\mu_n$ on $(\mathbb{R}^n, \mathcal{B}_n)$. Suppose that the sequence of probability measures ${(\mu_n)}_{n \geqslant 1}$ is consistent, in the sense that $\mu_{n+1}(A \times \mathbb{R}) = \mu_n(A)$ for every $n \geqslant 1$ and every $A \in \mathcal{B}_n$. Then the theorem asserts that there exists a probability measure $\mu$ on $(\mathbb{R}^\mathbb{N}, \mathcal{B}_\infty)$ which extends all the $\mu_n$, in the sense that $\mu(A \times \mathbb{R}^\mathbb{N}) = \mu_n(A)$ for every $n \geqslant 1$ and every $A \in \mathcal{B}_n$.
Let's see how to apply this theorem to show the existence of a sequence of independent random variables ${(X_n)}_{n \geqslant 1}$ with $X_n \sim \nu_n$, where ${(\nu_n)}_{n \geqslant 1}$ is a given sequence of probability measures on $\mathbb{R}$. One takes the product measure $\mu_n = \nu_1 \otimes \cdots \otimes \nu_n$ for every $n \geqslant 1$. Then the consistency condition of ${(\mu_n)}_{n \geqslant 1}$ is easy to check. Then the Daniell-Kolmogorov extension theorem provides a probability measure $\mu$ on $\mathbb{R}^\mathbb{N}$ which extends the $\mu_n$. Take the probability space
$$
(\Omega, \mathcal{A}, \mathbb{P}) = (\mathbb{R}^\mathbb{N}, \mathcal{B}_\infty, \mu).
$$
An element $\omega$ of $\Omega$ is a sequence of real numbers $(\omega_1, \omega_2, \ldots)$. Then it suffices to define for each $n \geqslant 1$ the random variable $X_n$ on $(\Omega, \mathcal{A}, \mathbb{P})$ by $X_n(\omega) = \omega_n$. In other words the random sequence ${(X_n)}_{n \geqslant 1}$ is a $\mathbb{R}^\mathbb{N}$-valued random variable whose probability distribution is $\mu = \nu_1 \otimes \nu_2 \otimes \cdots$. The theorem guarantees the existence of this infinite product measure.
Could anyone offer a simple example of a nonexistent process?
I like this example: there does not exist a "non-trivial" martingale ${(M_n)}_{n \geqslant 1}$ such that $M_n$ takes its values in $\{0,1\}$ for every $n \geqslant 1$. Indeed that would mean that $M_n = \mathbf{1}_{A_n}$ for a certain event $A_n$, for every $n \geqslant 1$. The martingale condition is
$$
\mathbb{E}[M_{n+1} \mid M_1, \ldots, M_n] = \mathbb{E}[M_{n+1} \mid M_n] = M_n.
$$
We have
$$
\begin{align}
\mathbb{E}\bigl[(\mathbf{1}_{A_{n+1}}-\mathbf{1}_{A_{n}})^2\bigr] & =\mathbb{E}[\mathbf{1}_{A_{n+1}}^2]+\mathbb{E}[\mathbf{1}_{A_{n}}^2]- 2\mathbb{E}[\mathbf{1}_{A_{n+1}}\mathbf{1}_{A_{n}}] \\ & =\mathbb{E}[\mathbf{1}_{A_{n+1}}]+\mathbb{E}[\mathbf{1}_{A_{n}}]- 2\mathbb{E}[\mathbf{1}_{A_{n+1}}\mathbf{1}_{A_{n}}].
\end{align}
$$
But
$$
\mathbb{E}[\mathbf{1}_{A_{n+1}}] = \mathbb{E}\bigl[\mathbb{E}[\mathbf{1}_{A_{n+1}} \mid \mathbf{1}_{A_{n}}]\bigr] = \mathbb{E}[\mathbf{1}_{A_{n}}]
$$
and
$$
\mathbb{E}[\mathbf{1}_{A_{n+1}}\mathbf{1}_{A_{n}}] =
\mathbb{E}\bigl[\mathbb{E}[\mathbf{1}_{A_{n+1}}\mathbf{1}_{A_{n}} \mid \mathbf{1}_{A_{n}}]\bigr] =
\mathbb{E}\bigl[\mathbf{1}_{A_{n}}\mathbb{E}[\mathbf{1}_{A_{n+1}} \mid \mathbf{1}_{A_{n}}]\bigr] =
\mathbb{E}[\mathbf{1}_{A_{n}}^2] = \mathbb{E}[\mathbf{1}_{A_{n}}].
$$
Finally, $\mathbb{E}\bigl[(\mathbf{1}_{A_{n+1}}-\mathbf{1}_{A_{n}})^2\bigr] = 0$, which means that $A_{n+1} = A_n$ (almost surely): our martingale is "trivial".