Questions tagged [water]

For questions relating to water (H₂O), specifically its structure, properties, and uses in chemistry. For questions not about water but rather about solutions in water, use tags [aqueous-solution] or [solubility] instead.

Water, chemical formula H2O, is a common chemical compound on Earth, covering over two-thirds of the surface area of the planet (in either frozen or liquid form) and comprising 0.02% of the total mass of the Earth. The majority of lifeforms on the Earth depend on water and are primarily composed of it, and many natural mineral compounds contain water molecules in their basic structure. As such, water is a key component of many physical and chemical processes of interest to modern science.

Water is naturally produced by the oxidation of pure hydrogen gas by pure oxygen gas. This reaction, like many oxidation reactions, produces heat. It is also a byproduct of the reaction of most strong acids, containing an H+ ion, and strong bases, containing a hydroxide (OH-) ion. The remaining components of the acid and base generally produce a salt.

Because of the arrangement of the electrons of an oxygen atom, a water molecule has a "bent" structure, with the hydrogen atoms at a 105° angle to the oxygen and each other, instead of a linear 180° arrangement. Because of this, a partial positive charge can be observed on the side of the molecule containing the two hydrogens, and a partial negative charge directly opposite. These partial charges make each water molecule, in effect, a tiny magnet, which gives water several interesting properties.

Water is a polar solvent; the molecular structure and partial polar charges can break weaker chemical bonds, such as hydrogen bonds and some ionic bonds. This causes materials which have these bonds, such as many salts including table salt, to readily dissolve in water. This property makes water crucial for most biological processes, which use the water to carry nutrients and electrolytes dissolved within it.

Another interesting property caused by its molecular shape is the tendency to form a crystalline structure when frozen which is less dense (occupying more space) than the same mass of liquid water. This causes ice to float, but also causes problems when living organic tissues, which contain water, are frozen; the water expands, bursting and destroying the cells, damaging the tissue.

These properties, paired with water's abundance on Earth, cause many other compounds to incorporate water into their structures. Many minerals, composed of various metallic and nonmetallic solid elements, are "hydrated"; their molecular arrangement incorporates water molecules in the structure. The water can often be released by heating the mineral, which produces a material with different properties. The production of Portland cement, for instance, involves "dehydrating" limestone, creating anhydrous calcium carbonate powder. Re-adding water to the cement during the formation of concrete in effect "reconstitutes" the limestone.

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Why doesn't water burn?

Hydrogen is flammable, and for any fire to burn it needs oxygen. Why does a compound made of hydrogen and oxygen put out fires instead of catalyzing them? I understand that hydrogen and water are chemically different compounds, but what causes water…
Prageeth Saravanan
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Does water really 'go bad' after a couple of days?

Among my friends it is a sort of 'common wisdom' that you should throw away water after a couple of days if it was taken from the tap and stored in a bottle outside the fridge, because it has 'gone bad'. First of all, the couple of days is not very…
Michiel
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Is it true that heavy water is not blue?

I believe I saw this claim somewhere on the internet a long time ago. Specifically, it was claimed that the difference could be observed by filling one long, straight tube with light water and one with heavy water, and looking through both tubes…
Brian
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Why don't we explode after drinking water?

It is known that acid should be added to water and not the opposite because it results in an exothermic reaction. Our stomach contains HCl, so why don't we explode when we drink water?
Ram Keswani
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What is the pH of ice?

The pH of pure liquid water depends on temperature. It is about pH = 7.0 at room temperature, pH = 6.1 at 100 °C, and pH = 7.5 at 0 °C. What happens to the pH (or to the ion product) of pure water when it freezes? I assume that the proton transfer…
Horatio
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Why does ice water get colder when salt is added?

It is well known that when you add salt to ice, the ice not only melts but will actually get colder. From chemistry books, I've learned that salt will lower the freezing point of water. But I’m a little confused as to why it results in a drop in…
cspirou
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Are the lone pairs in water equivalent?

I've read that the oxygen atom in water is $\mathrm{sp^2}$ hybridized, such that one of the oxygen lone pairs should be in an $\mathrm{sp^2}$ orbital and the other should be in a pure p atomic orbital. First, am I correct about the lone pairs being…
jheindel
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Does heavy water taste sweet?

In this YouTube video from Cody's Lab, Cody claims that heavy water tastes sweet. He does some fairly convincing comparisons but still expresses a little doubt that the effect is real. Has this been studied by others? Is the effect verified and if…
matt_black
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Is methanol more acidic than water?

Methanol is slightly more acidic than water. Their $\mathrm{p}K_\mathrm{a}$ values, in water, are $15.5$ and $15.7$, respectively. All other aliphatic alcohols, however, are less acidic than water. Is the following reasoning correct? This is my…
Dissenter
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Why is fresh ice sticky?

Fresh ice cubes are almost instantly sticky and easily cling on to fabric and other similarly rough surfaces. A few minutes later, however, the effect almost completely disappears. What is the cause of this adhesion? Why does the effect vanish…
Tabish Mir
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A glass of water with ice-cubes in it. Where's the water the coldest; at the top or bottom?

Suppose that I fill a glass with ice water. As the ice melts, it cools the water around it. Given that cold water is denser than hot water, I would presume that the cold water would sink to the bottom … but it would warm as it sinks, reducing the…
ND Geek
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Effect of drinking ultra-pure water

What would be the effect if someone were to drink ultra-pure water with an electrical resistivity of $18 \, \mathrm{M} \Omega \! \cdot \! \text{cm}$? Would they immediately die? Would they just need to pee more? Would $\ce{CO2}$ from the air…
user15949
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What makes ice slippery?

I've heard and read (multiple times) two theories have have been around for a while, both of them obvious nonsense. One states that pressure and friction make the ice melt (turn to water) where the skater's blade comes in contact with it. This is…
Ricky
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Why is snow white?

I know that this is a rather ambiguous question; but my question is, whenever we take water and freeze it in the freezer, it still tends to stay clear. Since snow is just frozen water, why is it white? Is it due to contents of the air - i.e. dust -…
Asker123
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What happens if you cool water in a container too small for it to freeze?

Freezing a full bottle of water tends to shatter the glass bottle. What if you used something tougher than glass, like diamond? What would happen if you kept dropping the temperature, but restrained the liquid volume so it couldn't freeze and what…
tom
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