Questions tagged [temperature]

A measure of the average kinetic energy of the particles in a sample of matter; may be expressed either in kelvin (symbol K) or in degree Celsius (symbol °C).

The thermodynamic temperature (quantity symbol: T) is one of the base quantities in the International System of Quantities (ISQ), on which the International System of Units (SI) is based. Thermodynamic temperature can be measured with a primary thermometer, examples of which are constant volume gas thermometers, acoustic thermometers, or total radiation thermometers.

The unit of thermodynamic temperature is the kelvin (unit symbol: K), which is the fraction 1/273.16 of the thermodynamic temperature of the triple point of water.

The Celsius temperature (quantity symbol: t or ϑ) is defined as t = T − T0, where T is thermodynamic temperature (see above) and T0 := 273.15 K. The thermodynamic temperature T0 is exactly 0.01 K below the thermodynamic temperature of the triple point of water.

The unit name degree Celsius (unit symbol: °C) is a special name for the kelvin for use in stating values of Celsius temperature: 1 °C := 1 K

The units of thermodynamic and Celsius temperature difference or change are identical. Such differences or changes may be expressed either in kelvin (unit symbol K) or in degree Celsius (unit symbol °C).

The unit degree Rankine (unit symbol °R) is a non-SI unit of thermodynamic temperature T:
1 °R := 5/9 K.
The use of this unit is deprecated.

The unit degree Fahrenheit (unit symbol °F) is a non-SI unit of Fahrenheit temperature tF:
tF/°F := (9/5) (t/°C) + 32 = (9/5) (T/K) − 459.67
The use of this unit is deprecated.

It should be noted that the symbol K (for kelvin), the symbol °C (for degree Celsius), the symbol °R (for degree Rankine), and the symbol °F (for degree Fahrenheit) shall be preceded by a space when one expresses values of temperature.

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Why is absolute zero unattainable?

We were dealing with the Third Law of Thermodynamics in class, and my teacher mentioned something that we found quite fascinating: It is physically impossible to attain a temperature of zero kelvin (absolute zero). When we pressed him for the…
paracetamol
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A glass of water with ice-cubes in it. Where's the water the coldest; at the top or bottom?

Suppose that I fill a glass with ice water. As the ice melts, it cools the water around it. Given that cold water is denser than hot water, I would presume that the cold water would sink to the bottom … but it would warm as it sinks, reducing the…
ND Geek
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Why is −78 °C a magic temperature for organic reactions?

In many organic reactions that I have seen, running the reaction at $\mathrm{-78\ ^\circ C}$ seems to be quite a popular choice, but I've never seen any explanation for this. What makes this temperature such a popular choice?
ringo
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Why do we still need to know about the Rankine temperature scale?

I am learning process principles in chemical engineering and I was taught various temperature units like Fahrenheit, Celsius, Kelvin, and Rankine. I see the first three being used quite commonly, but I rarely see the fourth being used. Where is the…
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Why does water evaporate at room temperature?

When water temperature reaches $100\ ^\circ \mathrm{C}$, the molecules get so excited that the hydrogen atoms lose the bonds to the oxygen atom and therefore the water starts to become gas. I get that, but at room temperature ($23\ ^\circ…
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There's an absolute zero, is there an "absolute hot"?

This might be more of a physics question, but is there a ceiling on how hot things can get? What happens at this temperature?
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When can a molecule be considered freely rotating at room temperature?

This question sparked from a long discussion in chat about the nature of $\ce{H2O2}$ and whether that molecule can be considered to rotate around the $\ce{O-O}$ axis (and hence display axial chirality) or not. Considering two rather clear…
Jan
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What exactly is temperature?

I've read at many places that temperature is the average kinetic energy of particles present in an object. I just don't intuitively get how kinetic energy is connected with temperature. And how is heat connected with temperature then? Then what…
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What is the difference between "vapour" and "gas"?

I have read the definition of vapour on Wikipedia, but I don't seem to have a clear idea about the difference between a vapour and a gas. I know what it means when it says, "gas at a temperature lower than its critical temperature". In this graph,…
gobbledy-gook
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Does the Maxwell-Boltzmann distribution apply to gases only?

The Maxwell-Boltzmann distribution can be used to determine the fraction of particles with sufficient energy to react. I know that the curve applies to gaseous reactants and would like to know whether solids and/or liquids are also described by a…
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Is there an uncertainty associated with the value 0 K for absolute zero?

When I say absolute zero, I’m not talking about the hypothetical temperature 0 K; I’m talking about the temperature at which a thermodynamic system has the lowest energy. Everywhere I look, sites maintain that this should be –273.15 ºC, but I can’t…
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Why is the Haber process carried out at such high temperatures?

On a large scale, ammonia is prepared via the Haber process: $$\ce{N2(g) + 3H2(g)->2NH3(g)} \qquad \Delta _\mathrm{f}H^\circ = -46.1~\mathrm{kJ \cdot mol^{-1}}$$ The optimum conditions for the productions of ammonia are a pressure of…
Tabish Mir
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Why do helium balloons expand in volume as they go higher?

I realize as balloons go higher, the atmospheric pressure decreases, doing less to counteract the force of the gas particles pushing against the inner walls of the balloon. But at the same time, doesn't the outside temperature decrease, causing the…
Nick
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Why no thermal expansion for camping tents?

I know that solid materials expand when heated, which is called thermal expansion. But what is happening to tent square or tent canvas of (plastic?) camping tents? I have noticed, that during the day, when it’s hot, there is a lot of tension in the…
erik
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Are complex ions thermochromic?

Does raising the temperature of a complex ion (formed from a transition metal ion and ligand(s)) affect its color? For example, if the temperature of $\ce{[Cr(H2O)6]^3+}$ is raised, will its color change?
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