A random variable is a real-valued function, $X_j = h_j(y),\; y\in S_y$, where $S_y$ is the domain of the function. A function is fully determined by three things: its domain, its range, and its functional form. So let's check:
Although it is not mentioned, let's say that the $X$ variable and the $\sqrt n X_i$ r.v. have the same domain, say, the reals (that domain has nothing to do with the distribution they follow). Since they are both normally distributed, they have the same range (which is the "support" i.e. it is the domain of the distribution they follow), $(-\infty, \infty)$. Do they have the same functional form? Unlikely.
We have $X = \sum_{j=1}^nX_j = \sum_{i=1}^nh_j(y)$ while $X_i = \sqrt nh_i(y)$. For these to be identical we should have
$$\frac {1}{\sqrt n -1}\sum_{j\neq i}^nh_j(y) = h_i(y),\;\; \forall y$$
This relation may, or may not hold. So in general, writing $X=\sqrt n X_i$ is wrong.
But, they are identically distributed... what does that mean? A function becomes a random variable if its range has such properties which can be summarized by another function possessing certain properties, a "cumulative distribution function", and in our case by the latter's derivative, the probability density function also (since it exists). But we just saw that two random variables may have identical distributions and at the same time they may be different functions. To put it in symbols, for two r.v.'s,
$$Z = Y \Rightarrow Z\sim_d Y$$
(and so also $E(Z^r) = E(Y^r) \;\; \forall r$), but
$$Z\sim_d Y \nRightarrow Z = Y$$
Yet another way to think of it intuitively is the following: assume that $X_i$ acquires a specific value, say $x_i^*$. Is it true that then the other random variables will acquire such values so as we will necessarily have
$\sum_{j\neq}^nx^*_j = (\sqrt n-1) x_i^*$? No. Therefore, $X$ and $\sqrt nX_i$ are not identical functions.
See also
Can two random variables have the same distribution, yet be almost surely different?