Let's start from the basics. Variance tells us about the variability around the mean
$$
\operatorname{Var}(X) = E[(X - E[X])^2]
$$
You can generalize this concept to two variables, the covariance
$$
\operatorname{Cov}(X, Y) = E[(X - E[X]) (Y - E[Y])]
$$
where variance is a special case of it
$$
\operatorname{Cov}(X, X) = E[(X - E[X])^2]
$$
Correlation is just a normalized covariance so that it is bounded between -1 and 1,
$$
\operatorname{Corr}(X, Y) = \frac{\operatorname{Cov}(X, Y)}{\sigma_X \sigma_Y}
$$
Autocorrelation is just a special case of correlation.
Yes, you can calculate the expected value of the ratio of two variables and in some case, it might be a meaningful statistic, but it doesn't anymore measure the "spread" or "co-spread" of the variables.
You may be interested in reading the How would you explain covariance to someone who understands only the mean? thread.