I think your question's confusion stems from interpreting "rolling dice" as a "problem." Rolling dice is just rolling dice.
The binomial distribution is useful for describing the probabilities of a number of independent events occurring $x$ times out of $n$ attempts, each with probability $p$. If "an event" is rolling some number, say "rolling a 3" or "rolling a 4 or higher", then the binomial theorem can help you understand the probabilities of such events occurring. For example: what is the probability that a fair1 six-sided2 die will come up '3' exactly four times if I roll the die ten times?
$$\begin{array}{rcl}
x & = & 4\\
n & = & 10\\
p & = & \frac{1}{6}\\
P\left(X = 6|n,p\right) & = & {10! \choose 4!\left(10-4\right)!}\left(\frac{1}{6}\right)^{4}\left(1-\frac{1}{6}\right)^{10-4}=0.054\end{array}$$
By contrast the multinomial theorem gives a means of calculating the number of unique ways of ordering $n$ total things across $i$ types of those things, where the number of the first type of thing is $n_{1}$, the number of the second type of thing is $n_{2}$, etc. up to $n_{i}$. For example, suppose I roll 10 six sided dice, and obtain $5,6,5,1,5,6,3,2,1,2$, I have three '5's, two 'six's, two '1's, one '3' and two '2's, and I want to know how many unique ways I could have rolled that many '5's, '6's etc.:
$$\text{Unique permutations of $n$ rolls with above $i$ values} = {10! \choose 3!\times 2! \times 2! \times 1! \times 2!} = 75,600$$
So you can see that "rolling dice" is not a "problem", or at least not until we ask specific questions about particular kinds of behavior of dice rolls, and then the binomial distribution, or multinomial theorem, or some other statistical or mathematical tool may be useful for providing answers.
1 "Fair" means each side has an equal probability of coming up on a single roll.
2 There are dice with different numbers of sides.