In a binomial experiment, if we observe $x=0$ positive individual among $n$ individuals, then the proportion of positive individuals is significantly lower than $3/n$ with a type 1 error less than and very close to $5\%$. This fact, sometimes called the "rule of three", is a consequence of the inequalities $$\exp\left(-\frac{np}{1-p}\right) \leq \Pr(X=0) \leq \exp(-np).$$
Do you know other such basic easy rules for statistics? I find them very interesting and useful. This principle is not really a "rule of thumb" because it has a reliable theoretical foundation, but I don't see another tag for this question (I hope it is not off-topic)