Presumably, a "CLT-based confidence interval" of confidence $1-\alpha$ for a sample $x_1,\ldots, x_n$ drawn randomly from a distribution with mean $\mu$ and variance $\sigma^2$ means the interval for $\mu$ having endpoints $\bar x \pm Z_{\alpha/2} s/\sqrt{n}$ where $\bar x$ is the sample mean, $s^2$ is the unbiased estimator of $\sigma^2,$ and $Z_{\alpha/2}$ is the $\alpha/2$ quantile of the standard Normal distribution.
This interval, as a function of the sample, also is random; but we may evaluate its expected width,
$$E\left[|(\bar x - Z_{\alpha/2}s/\sqrt{n}) - (\bar x + Z_{\alpha/2}s/\sqrt{n})|\right] = 2 Z_{\alpha/2}\,E[s]/\sqrt{n}.$$
We know $E[s]$ is finite (because $E[s^2]=\sigma^2$ is assumed finite for the CLT) and underestimates $|\sigma|$ (by virtue of Jensen's Inequality). For guidance, note that when the distribution truly is Normal, the bias in this estimate is of the order $1/n.$ For anything but the smallest sample sizes, then, we may take $E[s]\approx \sigma$ in this analysis.
Consequently, the expected width of the confidence interval is $2 |Z_{\alpha/2}\,\sigma|/\sqrt{n}.$
When $1-\alpha=0.99,$ $\alpha/2 = 0.005$ and $Z_{\alpha/2} \approx -2.58,$ giving an expected width of $5.16\,\sigma.$ Anyone wishing to state a conservative rule of thumb will wish to overestimate this result and might want to add another fudge factor for all the approximations implied by use of the CLT and replacing $E[s]$ by $\sigma.$ They will also want to introduce simple, memorable coefficients. These considerations lead to replacing $5.16$ by the next largest integer, yielding the statement in the question.