An exponential family is defined using two ingredients: - a base density $q_0(x)$ - a number of sufficient statistics $S_i(x)$
The family is all probability densities which can be written as: $$ q(x| (\lambda)_i ) \propto q_0(x) \exp \left( \sum_i \lambda_i S_i(x) \right) $$
It is well known that the relationship between parameters $ (\lambda_i) $ and expected value of the sufficient statistics: $$ E_q( S_i(x) | (\lambda_i) ) = \frac{\int S_i (x) q_0(x) \exp \left( \sum_i \lambda_i S_i(x) \right) dx}{ \int q_0(x) \exp \left( \sum_i \lambda_i S_i(x) \right) dx} $$ is a bijection.
My question is whether this bijection furthermore reaches "all possible values" for $E_q( S_i(x) | (\lambda_i) )$. In my original question, I gave a very poor definition of this ensemble of "all possible values" which made it so that the answer to my question was, somewhat trivially, no.
To define, "all possible values", we have to consider the image of the vector-valued function:
$$ x \rightarrow \mathbf{S}(x) $$
A value in $\mathbb{R}^d$ can be reached by the expected value of $\mathbf{S}$ under a probability density $p(x)$ if and only if it is inside the convex hull of the image of $\mathbf{S}$.
The question is then: when does the expected value of $\mathbf{S}$ inside the exponential family also have this property of spanning the whole convex hull of the image of $\mathbf{S}$ ?
Here are two examples:
The gaussian family in n-dimensions: the sufficient statistics are all first and second moments. It is indeed the case that all first and second moments can be reached by a Gaussian.
The exponential family: $$ q(x|\lambda) = exp( - |x| + \lambda x^2 ) $$
does not reach all values for the second moment: values over the upper bound at $\lambda=0$ are not reached.
This second example makes me think that problems will occur in the tails, if they occur at all, but maybe that intuition is wrong.