As already noted by others, "a.s." stands for "almost surely". The wikipedia article quoted by @Matt is a good start for almost surely and its synonyms.
There is however a subtle distinction between almost surely (or with probability 1) to always [resp., between with probability zero to never].
Imagine an infinite series of i.i.d. random variables which are head a.s. (=with probability 1), tail with probability zero. It is possible in such an infinite series to have a finite number of tails although the probability for tail is 0, as the empirical distribution of the series remains 1-0 (only a finite number of instances out of infinitely many). On the other hand, when one says that the series is always head one means that not even a single tail occurs in the series.