The probability density function of a normal distribution is
$$f(x)={\frac {1}{\sqrt {2\pi }\sigma}}\;e^{-{\frac {(x-\mu )^{2}}{2\sigma ^{2}}}}.$$
In your case, $\mu=0$, $\sigma^ 2=\frac{1}{16}$ so you just need to replace these values.
To find the value of the pdf at 0 you need to substitute $x$ by 0 and compute.
Now it comes the more complicated part. Because the normal distribution is continuous, it can take an infinite amount of values, from $-\infty$ to $\infty$ in a continuous way. Therefore, the probability of a single point is always zero, so $P(x=0)=0$ but for any value of $x$ this holds. This happens for all continuous distributions. Then, in the case of continuous distributions, the probability of a single point $P(x=x_0)$ does not make sense, and we always talk about probability density (or mass), $f(x_0)$.