Following a clarification by the OP, it appears that a) we assume that the two variables follow jointly a bivariate normal and b) our interest is in the conditional distribution, which is then
$$Y_n\mid X_n=x \ \sim\ \mathcal{N}\left(\mu_y+\frac{\sigma_y}{\sigma_x}\rho_n( x - \mu_x),\, (1-\rho_n^2)\sigma_y^2\right)$$
Then we see that as $n \to \infty$, we have $\rho_n \to 1$, and the variance of the conditional distribution goes to zero. Intuitively, if correlation goes to unity, "knowing $x$" is enough to "know $y$" also.
But nowhere in the above do we get that $\text{Cov}(Y_n, X_n)$ is zero. Even at the limit covariance will remain equal to $\text{Cov}(Y_n, X_n) \to \sigma_y \sigma_x$.
Note that the conditional covariance (and then also the conditional correlation) is always zero, because,
$$\text{Cov}(Y_n, X_n \mid X_n =x) = E(Y_nX_n\mid X_n =x) - E(Y\mid X_n =x) E(X\mid X_n =x)$$
$$=xE(Y_n\mid X_n =x) - xE(Y\mid X_n =x) =0$$
This happens because by examining $X_n = x$ we have turned one of the random variables into a constant, and constants do not co-vary with anything.