The "second" eigenvalue is either
- the second largest eigenvalue
- the second smallest eigenvalue
after performing eigenvalue decomposition (which yields a set of eigenvectors with associated eigenvalues, and this set can be sorted by the eigenvalues)
depending on the exact context. Most often, it is the second largest (and if you go to the SAS documentation, this holds for varclus, too).
In many cases, experience has shown that the first eigenvalue captures uninteresting data, such as the document size. Then it is ignored, and the next eigenvectors are considered to be topics. In other cases, the smallest or second-smallest (often non-zero) eigenvalue is used.